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        | Prevention of seal failures   through proper design, material selection and maintenance   certainly minimizes the risk of failure. Attention to the condition of replaced   seals, as well as the equipment performance over time, will result in improved   process reliability, reduced operating costs and a safer work   environment. O-ring seals often fail prematurely in applications   because of improper design or compound selection. This section is designed to   provide the user with examples of common failure modes. By correctly identifying   the failure mode, changes in the design or seal material can lead to improved   seal performance.  From the end-user’s point of view, a seal can fail in   three (3) general ways:  
            Leaking Contamination Change in Appearance | 
      
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        | One major factor in possible seal failure is the extreme   and harsh environment in which seals are expected to perform.  The sealing   environment can consist of virtually anything from inert gases at room   temperatures to aggressive chemicals at very high temperatures. The sealing   environment may result in chemical degradation or swelling of the sealing   components. Elevated temperatures may cause seal degradation, swelling or   outgassing. And the pressure—or more often, the vacuum environments—can cause   outgassing and weight loss. Contributing factors to seal failure in the sealing   environment include:  
            Chemical— the type of chemical(s) in   service Thermal— the operating ranges of the   seal (also any thermal cycling) Pressure/Vacuum— the range of   pressures or vacuum levels in the process  | 
      
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        | Analysis of the seal application is crucial to the   understanding of possible failure. Most seal design is performed by component   suppliers and equipment manufacturers. The designs are refined as experience is   gained. As quickly as process technology changes, however, the experience gained   with seal design may not be relevant to the latest process technology. Vacuum   applications have historically relied on high levels of compression and gland   fill to reduce permeation and trapped gases. These techniques, when applied to   new materials, or at higher operating temperatures, can result in premature seal   failure. The seal design and application can provide   information about the cause of failure:  
            Static Seals— axial and radial,   confined or unconfined Dynamic Seals— axial (open-close) or   radial (reciprocating or rotary) Sealing Gland Dimensions— 
              
                shape   (square, trapezoidal, etc.)                compression                gland   fill                stretch                Installation Procedures— stretch | 
      
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            | Description: The seal or   parts of the seal exhibit a flat surface parallel to the direction or motion.   Loose particles and scrapes may be found on the seal surface. |  
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            | Contributing Factors: Rough   sealing surfaces. Excessive temperature. Process environment containing abrasive   particles. Dynamic motion. Poor elastomer surface finish. |  
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            | Suggested Solutions: Use   recommended gland surface finishes. Consider internally lubed elastomers.   Eliminate abrasive components. |  | 
      
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            | Description: The seal exhibits a flat-sided cross-section, the   flat sides correspoding to the mating seal surfaces. |  
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            | Contributing Factors: Excessive compression. Excessive temperature.   Incompletely cured elastomer. Elastomer with high compression set. Excessive   volume swell in chemical. |  
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            | Suggested Solutions: Low compression set elastomer. Proper gland design   for the specific elastomer. Confirm material compatibility. |  | 
      
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            | Description: The   seal may exhibit many signs of degradation including blisters, cracks, voids or   discoloration. In some cases, the degradation is observable only by measurement of   physical properties. |  
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            | Contributing Factors: Contributing   Factors: Incompatibility with the chemical and/or thermal   environment. |  
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            | Suggested Solutions: Selection of more chemically resistant   elastomer. |  | 
      
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            | Description: The seal exhibits blisters, pits or   pocks on its surface. Absorption of gas at high pressure and the subsequent   rapid decrease in pressure. The absorbed gas blisters and ruptures the elastomer   surface as the pressure is rapidly removed. |  
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            | Contributing Factors: Rapid pressure changes.   Low-modulus/hardness elastomer. |  
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            | Suggested Solutions: Higher-modulus/hardness elastomer. Slower   decompression (release of pressure). |  | 
      
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            | Description: The seal develops ragged edges (generally on the   low-pressure side) which appear tattered. |  
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            | Contributing Factors: Excessive clearances. Excessive pressure.   Low-modulus/hardness elastomer. Excessive gland fill. Irregular clearance gaps.   Sharp gland edges. Improper sizing. |  
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            | Suggested Solutions: Decrease clearances. Higher-modulus/hard-ness   elastomer. Proper gland design. Use of polymer backup rings. |  | 
      
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            | Description: The seal or parts of the seal may exhibit small   cuts, nicks or gashes. |  
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            | Contributing Factors: Sharp edges on glands or components. Improper sizing   of elastomer. Low-modulus/hardness elastomer. Elastomer surface   contamination. |  
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            | Suggested Solutions: Remove all sharp edges. Proper gland design. Proper   elastomer sizing. Higher-modulus/hardness elastomer. |  | 
      
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            | Description: This failure is often very difficult to detect from   examination of the seal. The seal may exhibit a decrease in cross-sectional   size. |  
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            | Contributing Factors: Improper or improperly cured elastomer. High vacuum   levels. Low hardness/plasticized elastomer. |  
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            | Suggested Solutions: Avoid plasticized elastomers. Ensure all seals are   properly post-cured to minimize outgassing. |  | 
      
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              | Description: The seal exhibits parallel flat surfaces (corresponding to the contact areas) and      may develop circumferential splits within the flattened surfaces. |  
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              | Contributing Factors: Improper design—failure to account for thermal or chemical volume changes,      or excessive compression. |  
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              | Suggested Solutions: Gland design should take into account material responses to chemical and thermal      environments. |  | 
      
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              | Description: The seal often exhibits discoloration, as well as powdered residue on the surface      and possible erosion of elastomer in the exposed areas. |  
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              | Contributing Factors: Chemical reactivity of the plasma. Ion bombardment (sputtering). Electron      bombardment (heating). Improper gland design. Incompatible seal material. |  
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              | Suggested Solutions: Plasma-compatible elastomer and compound. Minimize exposed area. Examine gland      design. |  | 
      
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              | Description: The seal exhibits cuts or marks which spiral around its circumference. |  
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              | Contributing Factors: Difficult or tight installation (static). Slow reciprocating speed.      Low-modulus/hardness elastomer. Irregular O-ring surface finish (including excessive      parting line). Excessive gland width. Irregular or rough gland surface finish. Inadequate      lubrication. |  
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              | Suggested Solutions: Correct installation procedures. Higher-modulus elastomer. Internally-lubed      elastomers. Proper gland design. Gland surface finish of 8–16 microinch RMS. Possible      use of polymer backup rings. |  | 
      
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              | Description: The seal may exhibit radial cracks located on the highest temperature surfaces.      In addition, certain elastomers may exhibit signs of softening—a shiny surface as a      result of excessive temperatures. |  
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              | Contributing Factors: Elastomer thermal properties. Excessive temperature excursions or cycling. |  
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              | Suggested Solutions: Selection of an elastomer with      improved thermal stability. Evaluation      of the possibility of cooling sealing surfaces. |  |